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CANCELLED: Improved Adhesion to Reinforcement Fibers In Peroxide-Cured EPDM Compounds

Thursday, October 14, 2010: 1:00 PM
Tim Clayfield, Dr1, Cristiano Bette2, Muthu Subramanian3, Antonio Batistini, Dr4, Sascha Rulhoff4 and Lester Yeong3, (1)Dow Elastomers, Dow Europe GmbH, Horgen, Switzerland, (2)Dow Europe GMBH, Horgen, Switzerland, (3)Dow Chemical, The Dow Chemical Company, Singapore, Singapore, (4)Dow Europe GmbH, Horgen, Switzerland
Fibres such as p-aramid fibres are used to reinforce belts and hoses made with EPDM, to increase the stiffness of the elastomer.  This paper describes that the addition of hydroxy-TEMPO to the peroxide-cured elastomer compound significantly increases the reinforcement effect of the fibres in the elastomer compound.  It has further been found that hydroxy-TEMPO can prevent the formation of black scorch in EPDM compounds, which is of wide industrial utility.  This paper also describes a useful method of preparing a masterbatch of hydroxy-TEMPO and derivatives in apolar polymers that reduces the problems of migration often seen in such masterbatches.