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Br-Butyl Rubber (Br-IIR) and Montmorillonite (MMT) Clay Nano Composites for Improved Barrier Properties

Wednesday, October 13, 2010: 1:45 PM
Arun Kumar1, Carol M.F. Barry2 and Joey L. Mead2, (1)Plastics Engineering, University of Massachusetts-Lowell, Dracut, MA, (2)Plastics Engineering, Center for High-rate Nanomanufacturing, Lowell, MA
Controlling gas permeation is continuing challenge, posing multiple issues from pressure loss in tires to degradation of food. Br-IIR has good gas impermeability compared to other elastomers and has application in tires or other applications where air pressure retention or gas impermeability is a priority. The gas impermeability properties could be further improved by the addition of modified nano-clays (MMT modified with quaternary ammonium salt).  This work investigates the effect of clay loadings on the air permeation of Br-IIR and nanoclay composites.  Other properties such as dynamic mechanical, rheological and swelling ratio were also studied and compared to a compound without nanoclay.